catena-Poly[[(diiodidocadmium)-μ-{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κ2N:N′}]N,N-dimethylformamide monosolvate]

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catena-Poly[[(diiodidocadmium)-μ-{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole-κ2 N:N′}] N,N-dimethyl­formamide monosolvate]

In the title complex, {[CdI(2)(C(11)H(10)N(4))]·C(3)H(7)NO}(n), the Cd(II) ion is four-coordinated by two N atoms from two 1-[(1H-benzimidazol-1-yl)meth-yl]-1H-imidazole (bmi) ligands and by two terminal I(-) anions in a distorted tetra-hedral geometry. One of the two I(-) anions is disordered over two sets of sites, with refined occupancies of 0.66 (5) and 0.34 (5). The Cd(II) ions are bridged...

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1H-Benzimidazol-2-ylmethyl phenyl ether

There are two mol-ecules in the asymmetric unit of the title compound, C(14)H(10)N(2)O: the dihedral angles between their aromatic ring planes are 47.4 (4) and 46.8 (3)°. In the crystal structure, mol-ecules are linked by N-H⋯N hydrogen bonds from the secondary nitro-gen N-H donor to the tertiary N-atom acceptor of a symmetry-related neighbour, resulting in hydrogen-bonded chains. The two indep...

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catena-Poly[iron(II)-bis­{μ-5-carb­oxy-2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-imidazole-4-carboxyl­ato}]

In the title coordination polymer, [Fe(C(8)H(6)N(5)O(4))(2)](n) {or [FeL(2)](n),where HL = 2-[(1H-1,2,4-triazol-1-yl) meth-yl]-1H-imidazole-4,5-dicarb-oxy-lic acid)}, the Fe(II) ion, located on an inversion centre, is six-coordinated by two O atoms and four N atoms from two L(-) ligands in a distorted octa-hedral geometry [Fe-O = 2.1452 (13), Fe-N = 2.1316 (14) and 2.2484 (15) Å]. There is an i...

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Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-imidazole-κN 3}dichlorido­cadmium hexa­hydrate

In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial positions, leading to an elongated octa-hedral environment. The two coordinating and two of the latti...

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catena-Poly[[dinitratocopper(II)]-μ-4,4′′-bis­(1H-benzimidazol-1-yl)-1,1′:4′,1′′-terphen­yl]

In the title one-dimensional coordination polymer, [Cu(NO(3))(2)(C(32)H(22)N(4))](n), the Cu(2+) ion (site symmetry 2) is coordinated by two nitrate O atoms and two N atoms from two 4,4'-bis-(benzoimidazol-1-yl)terphenyl (L) ligands in a distorted cis-CuN(2)O(2) square-planar coordination geometry. An alternative description of the metal coordination geometry, if long Cu-O contacts to the bonde...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811050823